Rate Constant Equation:
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The reaction rate constant (k) is a proportionality constant in the rate law that relates the reaction rate to the concentrations of reactants. It is specific to a particular reaction at a given temperature and provides quantitative information about reaction kinetics.
The calculator uses the rate law equation:
Where:
Explanation: The rate constant represents the intrinsic speed of a chemical reaction and is determined experimentally from rate measurements at known concentrations.
Details: The rate constant is crucial for predicting reaction rates, designing chemical reactors, understanding reaction mechanisms, and determining how reaction rates change with temperature (Arrhenius equation).
Tips: Enter reaction rate in M/s, concentrations in molarity (M), and reaction orders as determined experimentally. Ensure all values are positive and concentrations are non-zero when orders are positive.
Q1: What are typical units for rate constants?
A: Units vary with overall reaction order: M⁻¹s⁻¹ for second-order, s⁻¹ for first-order, M·s⁻¹ for zero-order reactions.
Q2: How are reaction orders determined?
A: Reaction orders are determined experimentally by measuring how reaction rate changes with concentration changes of each reactant.
Q3: Does temperature affect rate constant?
A: Yes, rate constants increase with temperature according to the Arrhenius equation: k = A·e^(-Ea/RT).
Q4: Can rate constant be negative?
A: No, rate constants are always positive values since they represent the speed of a reaction.
Q5: What is the difference between rate and rate constant?
A: Rate is the speed of reaction at specific concentrations, while rate constant is the proportionality factor that relates rate to concentrations.